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| Title: | Synthesis of N-hydroxysuccinimide from succinic acid and hydroxylammonium chloride using Amberlyst A21 as reusable solid base catalyst |
| Authors: | Le, Son Dinh
Nishimura, Shun
Ebitani, Kohki |
| Keywords: | N-hydroxysuccinimide
succinic acid
hydroxylammonium chloride
solid base catalyst |
| Issue Date: | 2018-01-22 |
| Publisher: | American Institute of Physics |
| Magazine name: | AIP Conference Proceedings |
| Volume: | 1929 |
| Number: | 1 |
| Start page: | 020017-1 |
| End page: | 020017-6 |
| DOI: | 10.1063/1.5021930 |
| Abstract: | Solid base catalysts were studied for the first time to synthesize N-hydroxysuccinimide (NHS) through the reaction of succinic acid with hydroxylammonium chloride. The highest yield of 42% (±3%) with 65% (±4%) selectivity toward NHS production was achieved by using Amberlyst A21, which is a weak base anion-exchange resin. The present catalyst could be recycled during five runs without significant decreases in activity. Also, efficacy for the Amberlyst A21 mediated reaction was also explored with other dicarboxylic acids such as phthalic acid, glutaric acid, and maleic acid. |
| Rights: | Copyright 2018 Authors. Published by AIP Publishing. Son Dinh Le, Shun Nishimura and Kohki Ebitani, AIP Conference Proceedings, 1929(1), 20017 (2018) and may be found at http://dx.doi.org/10.1063/1.5021930 |
| URI: | http://hdl.handle.net/10119/15747 |
| Material Type: | publisher |
| Appears in Collections: | c11-1. 会議発表論文 (Conference Papers)
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