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このアイテムの引用には次の識別子を使用してください:
http://hdl.handle.net/10119/9187
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タイトル: | Lateral distribution of N3 dye molecules on TiO_2(1 1 0) surface |
著者: | Ikeda, Masatoshi Koide, Naoki Han, Liyuan Pang, Chi Lun Sasahara, Akira Onishi, Hiroshi |
キーワード: | N3 Titanium dioxide Scanning tunneling microscopy Aggregation Autocorrelation analysis |
発行日: | 2008-12-11 |
出版者: | Elsevier |
誌名: | Journal of Photochemistry and Photobiology A: Chemistry |
巻: | 202 |
号: | 2-3 |
開始ページ: | 185 |
終了ページ: | 190 |
DOI: | 10.1016/j.jphotochem.2008.12.005 |
抄録: | The lateral distribution of Ru(4,4′-dicarboxy-2,2′-bipyridine)_2(NCS)_2 (N3) dye molecules on a titanium dioxide (TiO_2) surface was examined by using a scanning tunneling microscope. Pivalate ((CH_3)_3CCOO−) -covered rutile TiO_2(1 1 0) surfaces were immersed in acetonitrile containing the N3 dye. The N3 molecules which replaced the pivalates were observed as protrusions embedded in the pivalate monolayer. Two-dimensional radial distribution function indicated that the adsorbed N3 molecules tended to be aggregated. Trapping of an N3 molecule in the solution by a preadsorbed N3 molecule was proposed as a driving force for the aggregation. The hydrogen bonds between the carboxyl groups of two N3 molecules contribute to the trapping. |
Rights: | NOTICE: This is the author's version of a work accepted for publication by Elsevier. Masatoshi Ikeda, Naoki Koide, Liyuan Han, Chi Lun Pang, Akira Sasahara, and Hiroshi Onishi, Journal of Photochemistry and Photobiology A: Chemistry, 202(2-3), 2008, 185-190, http://dx.doi.org/10.1016/j.jphotochem.2008.12.005 |
URI: | http://hdl.handle.net/10119/9187 |
資料タイプ: | author |
出現コレクション: | c10-1. 雑誌掲載論文 (Journal Articles)
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